| 摘要: |
| 采用GC－MS联用分析技术从披针叶黄华总生物碱中分离鉴定出12个喹诺里西啶生物碱，即无叶豆碱，N－甲基金雀花碱，金雀花碱，白羽扇豆碱，黄华碱，臭豆碱，N－甲醛金雀花碱，Dodecahydro-7,14-methanodipyrido[1,2,-a:1′，2′－E][1.5]diazocine,Pyridine-acetyl-1,2,3,4-tetrahydro-5-(2-piperdinyl),7,14-Methano-2H,6H-dipyrido[1,2-a:1′-e][1,5]diaz,1,1-Dimethyl-3-(2-nitrophenyl),7,14-Methano-4H,6H-dipyrido[1,2-a:1′，2′-e][1,5]diaz。后5种化合物为首次从该植物中鉴定。 |
| 关键词: 野决明属 披针叶黄华 生物碱 GC-MS |
| DOI： |
| 分类号: |
| 基金项目:国家自然科学基金资助项目(39770571) |
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| Studies on chemical constitution of alkaloid from Thermopsis lancenolate |
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| Abstract: |
| Twelve quinolizidine-type alkaloids were isolated and identified from the total alkaloids of Thermopsis lancenolate by GC-MS.They are sparteine,caulophylline,cytisine,lupanine,thermopsine,anagyrine,N-formylcytisine,dodecahydro-7,14 methanodipyrido［1,2-a:1′,2′-E][1,5]diazocine,pyridine 1-acetyl-1,2,3,4-tetrahydro-5-(2-piperdinyl),7,14-methano-2H,6H-dipyrido［1,2-a:1′,2′-E][1,5]diaz,1,1-dimethyl-3-(2-nitrophenyl),7,14-methano-4H,6H-dipyrido［1,2-a:1′,2′-e][1,5]diaz.The last five compounds were determined from this species for the firsy time. |
| Key words: thermopsis Thermopsis lancenolate alkaloids GC-MS |
