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有机化合物的构性相关分析Ⅲ.卤代烃的构性相关分析
傅建熙1, 周 乐1, 马养民1
西北农林科技大学 生命科学学院
摘要:
简明地描述了极性共价键概念,并用成键原子的电负性差说明了卤代烃分子中的C—X(X为F,Cl,Br,I)键都是极性共价键。同时,在有机化学构性相关理论指导下,对卤代烃进行了较系统的构性相关分析,揭示了它们构性之间的因果关系规律,并将其化学性质归纳成3大类:官能团的反应,烃基的反应,官能团和烃基共同参与的反应。
关键词:  卤代烃,极性,电负性,构性相关分析
DOI:
分类号:
基金项目:
The interrelation analysis between stracture-property of organic compounds Ⅲ.The interrelation analysis between structure-property of alkyl halides
Abstract:
Polarized covalent bonds is described briefly. And it is explained that C—X bonds in alkyl halides are polarized covalent bonds with the electronegativity difference between atom-formed bonds.The interrelation analysis between structure-property of alkyl halides is done systematically by means of the interrelation theory between structure-property of organic compounds. The law of causality between structure-property of alkyl halides is brought to light.And chem ical reactions of alky halides are divided into 3 kinds: functional group reactions,hydrocarbon radical reactions and reactions of functional group and hydrocarbon radical together.
Key words:  alkyl halides  polarizability  electronegativity  the interrelation analysis between structure-property

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