| 摘要: |
| 基于松油烯-4-醇的研究成果，合成了其酰胺、硫酯、酯、醚等11种衍生物。检索结果表明，其中1-(1-甲基-1-羟基)乙基-4-甲基-3-环己烯基甲酸甲酯、1-(1-甲基-1-羟基)乙基-4-甲基-3-环己烯基甲酸乙硫酯、N，N-二甲基-[1-(1-甲基-1-羟基)乙基-4-甲基-3-环己烯基]甲酰胺、4-甲基-4-乙硫基环己基甲酸甲酯、4-甲基-4-乙硫基环己基甲酸乙硫酯和N，N-2-甲基-(4-甲基-4-乙硫基环己基)甲酰胺等6种化合物为新化合物。 |
| 关键词: 松油烯-4-醇 衍生物 化学合成 |
| DOI： |
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| 基金项目:国家863计划项目(2001AA246016)；国家“十五”科技攻关项目(2002BA516A04) |
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| Synthesis of new analogous insecticidal compound terpinen-4-ol |
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| Abstract: |
| Terpinen-4-ol is one of the major insecticidal compounds extracted from essential oil of Sabina vulgaris Ant..A series of amidate,thioester,ester,ether analogues of Terpinen-4-ol,10 compounds were synthesized for insecticidal activity screening.6 compounds of them,1-(1-methyl-1-hydroxyl) ethyl-4-methyl-3-cyclohexocarboxilic esters,1-(1-methyl-1-hydroxyl)ethyl-4-methyl-3-cyclohexocarboxilic thioester,N,N-dimethyl-1-(1-methyl-1-hydroxyl)ethyl -4-methyl-3-cyclohexocarboxilic amide,4-methyl-4-ethylsulfide cyclohexyl methyl formiate,4-methyl-4-ethylsulfide cyclohexyl ethyl thioester formic acid,N,N-dimethyl-(4-methyl-4-ethylsulfide cyclohexyl)-formamide,are new synthesized compounds. |
| Key words: terpinen-4-ol analogues chemical synthesis |
