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胡敏酸-铜复合物热分解特征的研究
杨亚提1, 张一平2, 白锦鳞1
1.西北农业大学 基础科学系;2.西北农业大学 资源与环境科学系
摘要:
运用差热分析法(DTA)对3种土壤胡敏酸-铜复合物的热分解特征进行了分析。结果表明;络合物与吸附物的热解曲线都有共同相似的热效应峰,DTA曲线的第1,2放热峰可作为区分络合物与吸附物的特征峰。随结合物中配位数(x)及吸附物中含铜量的增加,DTA曲线第1,2放热峰面积及焓变值(△H)均增大。
关键词:  胡敏酸,络合物,吸附物,铜,热分析
DOI:
分类号:S153.6
基金项目:
Pyrolytic Characteristics of Humic Acid-Copper Compound Substances
Yang Yati  Zhang Yiping  Bai Jinlin  Lu Dagong
Abstract:
Three kinds of soil humic acid一copper compound substanees were,with differential thermal analysis(DTA)method,divided into two types of complexes and adsorbed substances.Pyrolytic curves of both showed similar heat effect peaks.The first and the seeond exothermic peaks of DTA curves were the feature peaks which can be used to distinguish complexes from adsorbed substanees.The areas and enthalpy change values(△H)of the both peaks inereased with the inerease of coordination number (x) of the complexes and copper contents of the adsorbed substanee.
Key words:  humic acid,complexes,adsorbed substance,copper,pyrolytic