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砂地柏果实中2种二萜类杀虫活性成分的分离
朱海云1,2, 李广泽1, 廉应江1
1.西北农林科技大学 无公害农药研究服务中心;2.宝鸡文理学院 化学化工系
摘要:
以粘虫幼虫为试虫,采用活性跟踪法,从砂地柏(Sabina vulgaris Ant.)果实中分离出2种二萜化合物,经MS,1H-NMR和13C-NMR鉴定为4-表-松香醛和7,13-松香二烯-3-酮。活性测试结果表明,0.005 g/mL 4-表-松香醛和7,13-松香二烯-3-酮对3龄粘虫均具有较强的拒食及一定的毒杀活性。
关键词:  砂地柏  杀虫活性  二萜化合物  4-表-松香醛  7,13-松香二烯-3-酮
DOI:
分类号:
基金项目:国家自然科学基金资助项目(39970506);国家“863”计划项目(2001AA246016);国家“十五”攻关项目(2002BA516A04)
Isolation and structural identification of two insecticidal diterpenoids from fruits of Sabina vulgaris Ant.
Abstract:
With Mythimna separata Walker as the screening insect,two diterpenoids compounds were isolated from fruits of Sabina vulgaris Ant.According to the guidance of bioactivity assaying,their molecular structures were identified to be 4-epi-abietal and abieta-7,13-dien-3-one by MS,1H-NMR and 13C-NMR.The result of bioassay showed that 0.005 g/mL 4-epi-abietal and abieta-7,13-dien-3-one exhibited good antifeeding and some poisonous activity against the 3rd-instar Mythimna separata.
Key words:  Sabina vulgaris Ant.  insecticidal activity  diterpenoid compounds  4-epi-abietal  abieta-7,13-dien-3-one