摘要: |
以粘虫幼虫为试虫,采用活性跟踪法,从砂地柏(Sabina vulgaris Ant.)果实中分离出2种二萜化合物,经MS,1H-NMR和13C-NMR鉴定为4-表-松香醛和7,13-松香二烯-3-酮。活性测试结果表明,0.005 g/mL 4-表-松香醛和7,13-松香二烯-3-酮对3龄粘虫均具有较强的拒食及一定的毒杀活性。 |
关键词: 砂地柏 杀虫活性 二萜化合物 4-表-松香醛 7,13-松香二烯-3-酮 |
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基金项目:国家自然科学基金资助项目(39970506);国家“863”计划项目(2001AA246016);国家“十五”攻关项目(2002BA516A04) |
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Isolation and structural identification of two insecticidal diterpenoids from fruits of Sabina vulgaris Ant. |
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Abstract: |
With Mythimna separata Walker as the screening insect,two diterpenoids compounds were isolated from fruits of Sabina vulgaris Ant.According to the guidance of bioactivity assaying,their molecular structures were identified to be 4-epi-abietal and abieta-7,13-dien-3-one by MS,1H-NMR and 13C-NMR.The result of bioassay showed that 0.005 g/mL 4-epi-abietal and abieta-7,13-dien-3-one exhibited good antifeeding and some poisonous activity against the 3rd-instar Mythimna separata. |
Key words: Sabina vulgaris Ant. insecticidal activity diterpenoid compounds 4-epi-abietal abieta-7,13-dien-3-one |