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有机化合物的构性相关分析Ⅰ.烯烃和炔烃的构性相关分析
傅建熙1, 马养民1
西北农林科技大学 基础科学系
摘要:
阐述了烯烃和炔烃分子中的π-分子轨道,并且根据有机化合物的构性相关理论对烯烃和炔烃进行了系统的构性相关分析。经过分析将烯烃和炔烃的化学性质归纳成为3大类:官能团的反应,烃基的反应和端基炔的特殊反应,从而增强了烯烃和炔烃化学的规律性和科学性。
关键词:  π-分子轨道  构性相关理论  构性相关分析  烯烃  炔烃
DOI:
分类号:
基金项目:
The interrelation analysis between structure-property of organic compounds:Ⅰ.The interrelation analysis between structure-property of alkenes and alkynes
FU Jian xi  MA Yang min
Abstract:
π-Molecular orbitals of alkenes and alkynes are expounded. And the interrelation analysis between structure-property of alkenes and alkynes is done systematically by means of the interrelation theory between structure-property of organic compounds. The chemical properties of alkenes and alkynes are induced to 3 kinds through analysis: reactions of functional group, reactions of hydrocarbon radical,special reactions of extremity alkynes.And the regularity and scientism of alkene and alkyne chemistries are enhanced.
Key words:  π-Molecular orbital  the interrelation theory between structure-property  the interrelation analysis between structure-property  alkene  alkyne