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氧化钛/活性炭纳米光催化剂氧化苯酚的研究
周广阔1,2, 冯贵颖1, 呼世斌1
1.西北农林科技大学 生命科学学院;2.杨凌职业技术学院 林学系
摘要:
以活性炭(AC)为载体,利用溶胶凝胶工艺制备氧化钛(TiO2)溶胶,通过浸渍法制备负载型TiO2/AC纳米光催化剂以及掺杂Fe3+和Cu2+的M-TiO2/AC纳米复合光催化剂。以紫外灯做光源,用制得的TiO2/AC纳米光催化剂对苯酚溶液进行光催化氧化降解试验,并研究了掺杂Fe3+和Cu2+的M-TiO2/AC纳米复合光催化剂对苯酚的催化活性;结果表明,在紫外光条件下,TiO2/AC纳米光催化剂对苯酚的降解率达99%,较目光条件下高;掺杂Fe3+能提高M—TiO2/AC纳米复合光催化剂对笨酚的催化活性。
关键词:  纳米光催化剂  光催化氧化  苯酚  金属离子
DOI:
分类号:
基金项目:
Photocatalytic oxidation of phenol in water by TiO2/AC nanocomposite
Abstract:
Titanium dioxide/activated carbon prepared by the sol-gel method and a supported catalyst TiO2/AC prepared by impregnation method were used as a photocatalyst in the reaction of phenol decomposition in water under Uv-lamp radiation.The nano-photocatalysts TiO2/AC and nanocomposite Cu2+ and Fe3+-doped M-TiO2/AC were discussed.The results showed that the nano-photocatalysts TiO2/AC have high photocatalytic activity for phenol concentration;The total removal efficiency was 99% under Uv-light radiation;And the experiment of Fe3+-doped nanocomposite photocatalysts M-TiO2/AC thin film showed the high activity compared with the un-doped one,while the Cu2+-doped method is not available for TiO2/ AC.
Key words:  nanocomposite  TiO2  photocatalytic oxidation  phenol  mental iron